Pour the hot chocolate mixture over the dry ingredients, and whisk until combined- the mixture will be very thick at this point, and it doesn't have to be fully mixed through. Then stir in the buttermilk, eggs, and vanilla extract and whisk until combined and smooth. Pour the batter into your prepared cake pans, and bake for 30-35 minutes, or until a toothpick comes out with just a few crumbs clinging to it, or an instant read thermometer reads 200 degrees when inserted in the center of the cake. Cool the cake completely before frosting it. Optionally, remove the cakes from the pans while hot and wrap tightly in plastic wrap, allowing the cakes to cool at room temp while wrapped. See tips on this process above.